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Comptes rendus academie des sciences, chimie, t.10, fascicule 8, aout 2007 : metaux en biocatalyse : d

Couverture du livre « Comptes rendus academie des sciences, chimie, t.10, fascicule 8, aout 2007 : metaux en biocatalyse : d » de Marc Fontecave aux éditions Elsevier
  • Date de parution :
  • Editeur : Elsevier
  • EAN : 9782756202303
  • Série : (-)
  • Support : Revue
Résumé:

Avant-propos/Foreword. Second generation artificial hydrogenases based on the biotin-avidin technology: improving selectivity and organic solvent tolerance by introduction of an (R)-proline spacer. New biocatalysts mimicking oxidative hemoproteins: Hemoabzymes. Diiron-containing metalloproteins:... Voir plus

Avant-propos/Foreword. Second generation artificial hydrogenases based on the biotin-avidin technology: improving selectivity and organic solvent tolerance by introduction of an (R)-proline spacer. New biocatalysts mimicking oxidative hemoproteins: Hemoabzymes. Diiron-containing metalloproteins: developing functional models. Iridium aminyl radical complexes as catalysts for the catalytic dehydrogenation of primary hydroxyl functions in natural products. Xanthine oxidase-assisted catalysis by dopamine -hydroxylase: mechanistic considerations on the role of superoxide anion. ATP- and redox-induced conformational changes in the activator of the radical enzyme 2-hydroxyisocaproyl-CoA dehydratase. Isoprenoid biosynthesis via the methylerythritol phosphate pathway: GcpE and LytB, two novel iron-sulphur proteins. Characterization of the DNA repair spore photoproduct lyase enzyme from Clostridium acetobutylicum: a radical-SAM enzyme. Hybrid density functional study of the oxidized states of NiFe-hydrogenase.

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